Despite its many advantages, the production of lithopone is not without its challenges. The raw materials used to make lithopone, particularly zinc sulfide, can be expensive and difficult to source. In addition, the production process itself can be complex and energy-intensive, requiring specialized equipment and skilled workers to operate. As a result, lithopone manufacturers must carefully manage their operations to ensure they remain competitive in the market.
Although barium sulfate is almost completely inert, zinc sulfide degrades upon exposure to UV light, leading to darkening of the pigment. The severity of this UV reaction is dependent on a combination of two factors; how much zinc sulfide makes up the pigments formulation, and its total accumulated UV exposure. Depending on these factors the pigment itself can vary in shade over time, ranging from pure white all the way to grey or even black. To suppress this effect, a dopant may be used, such as a small amount of cobalt salts, which would be added to the formulation. This process creates cobalt-doped zinc sulfide. The cobalt salts help to stabilize zinc sulfide so it will not have as severe a reaction to UV exposure.
Polyvinyl Butyral Resin (PVB) is a solvent Resin synthesized by the acetal reaction of Polyvinyl Alcohol (PVA) and butyraldehyde in contact with coal.
Because Pvb Resin itself contains a lot of hydroxyl groups, it can bridge with some thermosetting resins to improve the properties of chemicals and film hardness.
Because PVB resin has the above excellent characteristics, it is widely used in adhesive safety glass intermediate film of automobile and building, rust cutting primer, baking paint, wood paint, printing ink, adhesive of electronic ceramics and printed circuit board, adhesive between metal and metal, between metal and plastic, modifier of hot-melt adhesive, iron dimension waterproof processing of textile, etc. A variety of new industrial applications are also continuously developed and applied.
The general characteristics of PVB are as follows:
The appearance of polyvinyl butyral (PVB) resin is white spherical porous particles or powder, and its specific gravity is 1:1; However, the filling density is only 0.20 ~ 0.35g/ml.
Thermal properties
The glass transfer temperature (TG) of polyvinyl butyral (PVB) resin ranges from 50 ℃ of low degree of recombination to 90 ℃ of high degree of recombination; The glass transfer temperature can also be adjusted by adding an appropriate amount of Plasticizer to reduce it below 10 ℃.
Mechanical properties
The coating of polyvinyl butyral (PVB) resin has good water resistance, water resistance and oil resistance (it is resistant to aliphatic, mineral, animal and vegetable oils, but not to sesame oil). PVB is widely used in printing inks and coatings because it contains high hydroxyl groups and has good dispersibility to pigments.
In addition, its chemical structure contains both hydrophobic acetal and acetic ACID groups and hydrophilic hydroxyl groups, so PVB has good adhesion to glass, metal, plastic, leather and wood.
Chemical reaction
Any chemical that can react with secondary alcohol will also react with PVB. Therefore, in many applications of PVB, it is often used with thermosetting resin to bridge and harden with the hydroxyl group of PVB, so as to achieve the characteristics of chemical resistance, solvent resistance and water resistance.
Of course, films with different characteristics (such as hardness, toughness, impact resistance, etc.) can be prepared according to different types of thermosetting resin and different mixing ratio with PVB.
Safety properties
Always start by making sure the oil seal is facing the right direction. The oil seal must be positioned with its spring to the side of the medium to be sealed. The oil seal must then be pressed into the bore. It must fit tightly (H8 in the groove is recommended). Use appropriate tools for this, such as an impact socket set, to ensure that the force is applied evenly during pressing. The oil seal must never be hammered into the bore with brute force, but eased in.
Standard springs are made of carbon steel. We use stainless-steel springs for our GR and GRST oil seals made from FKM rubber. In some rare cases, an O-ring is even used as a spring element. Standard PTFE lip seals are not fitted with springs.
The most common oil seals are the ERIKS types R, RST, M and MST, which correspond respectively to types A, AS, B and BS according to DIN 3760/ISO 6194.
There is a British Standard laid down for the control of synthetic rubbers. BS 3574 (1989) helps to determine shelf life – for instance, Nitrile (NBR) and Polyacrylic (ACM) are Group ‘B’ rubbers and have a 7-year life, whilst Silicone (VMQ) and Fluoroelastomers (Viton®) are Group ‘C’ rubbers and have a 10-year shelf life. PTFE and Leather do not come into this category but like the others should be kept in the original packing for as long as possible away from direct light, dust, and humidity. Ozone, which can also be produced by battery-driven forklift trucks has a very bad effect on synthetic rubbers. Finally, protect the sealing lip – DO NOT hang the seals on nails, wire etc.
As shown in Figure 1, sealing devices come in two types: contact and non-contact.
Oil seals are among the major contact type sealing devices.